Caustic soda is the most widely used
chemical for cleaning in place. During operation, caustic soda reacts with fats
and proteins. This splits them into smaller molecules and creating foaming
compounds (saponification process). Foaming compounds reduce the surface
tension of water, increasing the cleansing ability.
1) The pure liquid caustic solution do not
foam
2) Presence of surface active agent (also
called surfactant) is needed to produce foam
3) Surfactants are amphi-polar, composed of
a non-polar hydrophobic tail and a polar hydrophilic head. They reduce water
surface tension and thereby emulsify the fats
4) Foam is created when air is mixed in
water with its surface tension is reduced, producing bubbles. Many substances,
besides soap and detergents, will reduce surface tension
5) Foams are essentially unstable and tend
to collapse, separating air and liquid
High organic loads during the caustic phase
of the CIP cleaning causes the saponification conditions that then result in
excessive foaming. Thus excessive foaming is often associated with product
contamination though other factors such as air entrainment via leaking pump
seals or the use of totally softened water should also be checked as
possibilities.
Foam, if not held under control will
decrease cleaning performance, as it is difficult to rinse, causes cavitation
in pumps as a result of air introduction into the lines, reduces the efficiency
of the cleaning agent. Foaming also causes carry-over and can be very dangerous
because hot and concentrated solution are used. It will cause the tank (if the
CIP liquid is recovered) or drain pipe (if drained to wastewater treatment) to
overfill / overflow
So, how do we avoid such a situation ? My
recommendations are as follows:
1) Completely drain out the product inside
the lines and equipment - recover and use up all the product inside the
pipelines and tanks prior to cleaning. Any leftover product forms the soiling
on the system whose fats and protein content cause the foaming reaction. Pipe
pigging may be considered to empty out long lengths of pipelines. Savings from
the product recovered and reduction in waste water load can justify its
investment2) Ensure correct CIP operation during the pre-rinse phase - the right turbulence / velocity must be flowing through all parts of the system being cleaned with sufficient time to remove the majority of the soil. This also saves on the chemical consumption for the succeeding phases
3) Review equipment and pipelines installation design for proper drainage slopes - no liquid should be left stagnant on the lines when the equipment stops
4) Defoamers - added to cleaning solutions. Non-ionic surface active agents become effective defoamers at temperatures where they are no longer soluble in water. Silicones although are good defoamers, are typically avoided, as most have a tendency to adhere to surfaces
5) Use of other cleaning agents - may substantially increase the cost as other chemicals are much more expensive than caustic
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